HIGHLY COORDINATE ORGANOSILICON COMPOUNDS IN SYNTHESIS: NEW ENTRY TO S,N-ACETALS BY SELECTIVE REDUCTION OF ALKYLTHIOMETHYLENIMINIUM SALTS BY USE OF TRIMETHOXYSILANE AND DILITHIUM 2,3-BUTANDIOLATE

DOI: 10.1016/S0040-4039(00)82188-7

Source and publish data:

Tetrahedron Letters p. 5771 - 5774 (1988)

Update date:2022-08-04

Topics: Organosilicon compounds S,N-Acetals

Authors:

Tominaga, Yoshinori

Matsuoka, Yoshiki

Hayashida, Hisashi

Kohra, Shinya

Hosomi, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)82188-7

Reduction of alkylthiomethyleniminium iodides proceeds smoothly by use of trimethoxysilane and dilithium 2,3-butandiolate in tetrahydrofuran at 0 deg C to give the corresponding S,N-acetals selectively in high yield.

Full text of DOI:10.1016/S0040-4039(00)82188-7

Products guided by the article

Product name:4-[Ethylsulfanyl-(4-methoxy-phenyl)-methylene]-morpholin-4-ium; iodide

Cas No:120290-10-0

R&D Labs maybe for 120290-10-0

Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
Taizhou Shengxing Chempharm Co.,Ltd

Contact:+86-576-88516600

Address:Yantou Chemical Zone Jiaojiang Taizhou Zhejiang China
Shanghai Forever Biotech Co., Ltd.

Contact:+86-21-69734790

Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China
Yueyang Hudex Pharmaceuticals Ltd.

Contact:0730-8748800

Address:Wujiang Bridge，Yueyang Economy & Technology Development Zone

Relevant to this article

Inhibitory activity of catechin metabolites produced by intestinal microbiota on proliferation of heLa cells

Doi:10.1248/bpb.b17-00127
(2017)
Photochromic blockers of voltage-gated potassium channels

Doi:10.1002/anie.200904504
(2009)
Hydrohydrazination of Arylalkynes Catalyzed by an Expanded Ring N-Heterocyclic Carbene (er-NHC) Gold Complex under Solvent-Free Conditions

Doi:10.1002/adsc.201500658
(2016)
Spin Trapping with Thiocarbonyl Compounds

Doi:10.1039/f19888403347
(1988)
Synthesis and Structure of Carbonyliron Complexes of Allenecarboxylates and Allenic Lactones

Doi:10.1002/hlca.19880710307
(1988)
A series of multinuclear homo- and heterometallic complexes with bridging tellurolato ligands derived from [Cp^*Ir(CO)(TeTol)₂] (Cp^* = η⁵-C₅Me₅, Tol = p-tolyl)

Doi:10.1016/j.jorganchem.2009.09.038
(2010)

Article Doi