HIGHLY COORDINATE ORGANOSILICON COMPOUNDS IN SYNTHESIS: NEW ENTRY TO S,N-ACETALS BY SELECTIVE REDUCTION OF ALKYLTHIOMETHYLENIMINIUM SALTS BY USE OF TRIMETHOXYSILANE AND DILITHIUM 2,3-BUTANDIOLATE

DOI: 10.1016/S0040-4039(00)82188-7

Source and publish data:

Tetrahedron Letters p. 5771 - 5774 (1988)

Update date:2022-08-04

Topics: Organosilicon compounds S,N-Acetals

Authors:

Tominaga, Yoshinori

Matsuoka, Yoshiki

Hayashida, Hisashi

Kohra, Shinya

Hosomi, Akira

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Article abstract of DOI:10.1016/S0040-4039(00)82188-7

Reduction of alkylthiomethyleniminium iodides proceeds smoothly by use of trimethoxysilane and dilithium 2,3-butandiolate in tetrahydrofuran at 0 deg C to give the corresponding S,N-acetals selectively in high yield.

Full text of DOI:10.1016/S0040-4039(00)82188-7

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Product name:4-[Ethylsulfanyl-(4-methoxy-phenyl)-methylene]-morpholin-4-ium; iodide

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