INTRAMOLECULAR HYDROGEN SHIFT IN 3-O-BENZYL-6-DEOXY-D-HEXOFURANOSYL-6 RADICALS AND A CRITERION FOR DETERMINATION OF THE CONFIGURATION AT 1'-POSITION OF 6-DEOXY-3-O-(1-PHENYLALKYL)-1,2-O-ISOPROPYLIDENE-D-ALLOFURANOSES

DOI: 10.1016/S0040-4039(00)80742-X

Source and publish data:

Tetrahedron Letters p. 5297 - 5300 (1988)

Update date:2022-08-05

Topics:

Authors:

Araki, Younosuke

Endo, Tadatoshi

Arai, Yoshifusa

Tanji, Masaki

Ishido, Yoshiharu

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Article abstract of DOI:10.1016/S0040-4039(00)80742-X

The Bu3SnH - AIBN induced radical additions of 5-O-acetyl-3-O-benzyl-6-deoxy-6-iodo-1,2-O-isopropylidene-α-D-allofuranose (2) to electron deficient olefins gave 6-deoxy-3-O-(1-phenylalkyl) derivatives as by-products.The configurations at C-1' of them were

Full text of DOI:10.1016/S0040-4039(00)80742-X

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