Ring-opening Hydroformylation of α-Cyclopropylstyrene by HMn(CO)5, and Structure of a Novel Mn2(CO)9(η1-Aldehyde) Complex

DOI: 10.1039/c39890000261

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 261 - 263 (1989)

Update date:2022-08-03

Topics:

Authors:

Bullock, R. Morris

Rappoli, Brian J.

Samsel, Edward G.

Rheingold, Arnold L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39890000261

An η¹-aldehyde complex, Mn2(CO)9, was isolated from the reaction of α-cyclopropylstyrene with wet HMn(CO)5; the crystal structure of this unusual compound confirmed the η¹ (?) bonding of the aldehyde oxygen as an equatorial ligand on Mn2(CO)9.

Full text of DOI:10.1039/c39890000261

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Mn2(CO)9(η1-HCOCH2CH2CH=C(Ph)Me)

Cas No:120307-15-5

R&D Labs maybe for 120307-15-5

Hybio Pharmaceutica Co.,Ltd

website:http://www.hybio.com.cn

Contact:+86 755 26588093

Address:No.9 Linkong West Street, Hengdian Street, Huangpi District, Wuhan City, China.
Yingkou Sanzheng Organic Chemical Co. Ltd.

Contact:+86-417-3638818

Address:25 Gengxinli Village, Daqing Road, Yingkou, Liaoning, China
zhenjiang runjing high purity chemical co ltd

Contact:+86-511-83361155

Address:No.8.haixi road,international chemical park
WUHAN RISON TRADING CO.,LTD

Contact:0086-27-83607103/83642615

Address:No.498, Jianshe Ave, Wuhan, China
Jinan Yijialian Economic and Trade Development Co., Ltd.

Contact:+86 0531-66729596

Address:jinan

Relevant to this article

Selection of protecting groups and synthesis of a β-1,4-GlcNAc-β- 1,4-GlcN unit

Doi:10.1007/s00706-009-0172-0
(2009)
Tetrahydroisoquinoline-7-carboxamide Derivatives as New Selective Discoidin Domain Receptor 1 (DDR1) Inhibitors

Doi:10.1021/acsmedchemlett.6b00497
(2017)
Reaction between isocyanides and nitrostyrenes in water: a novel and efficient synthesis of 5-(alkylamino)-4-aryl-3-isoxazolecarboxamides

Doi:10.1016/j.tetlet.2009.09.069
(2009)
Anti-malarial activity of new N-acetyl-l-leucyl-l-leucyl-l-norleucinal (ALLN) derivatives against Plasmodium falciparum

Doi:10.1016/j.bmcl.2012.12.100
(2013)
Substituent Effects on the Spectral, Acid-Base, and Redox Properties of Indolyl Radicals: A Pulse Radiolysis Study

Doi:10.1021/j100195a029
(1992)
Rhodium Carbenoid Mediated Cyclizations of o-Alkynyl-Substituted α-Diazoacetophenones

Doi:10.1021/jo00044a032
(1992)

Article Doi