Ring-opening Hydroformylation of α-Cyclopropylstyrene by HMn(CO)5, and Structure of a Novel Mn2(CO)9(η1-Aldehyde) Complex

DOI: 10.1039/c39890000261

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 261 - 263 (1989)

Update date:2022-08-03

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Authors:

Bullock, R. Morris

Rappoli, Brian J.

Samsel, Edward G.

Rheingold, Arnold L.

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Article abstract of DOI:10.1039/c39890000261

An η¹-aldehyde complex, Mn2(CO)9, was isolated from the reaction of α-cyclopropylstyrene with wet HMn(CO)5; the crystal structure of this unusual compound confirmed the η¹ (?) bonding of the aldehyde oxygen as an equatorial ligand on Mn2(CO)9.

Full text of DOI:10.1039/c39890000261

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