1,3-DIPOLAR CYCLOADDITION OF 2-BENZYLIDENEINDAN-1,3-DIONE α-OXIDE TO OLEFINS

DOI: 10.1007/BF00479360

Source and publish data:

Chemistry of Heterocyclic Compounds p. 1166 - 1169 (1987)

Update date:2022-08-04

Topics:

Authors:

Krysin, M. Yu.

Anokhina, I. K.

Zalukaev, L. P.

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Article abstract of DOI:10.1007/BF00479360

A carbonyl ylid, which reacts with maleic anhydride, N-phenylmaleinimide, and β-nitrostyrene to form adducts resulting from 1,3-dipolar cycloaddition, is formed reversibly when 2-benzylideneindan-1,3-dione α-oxide is heated (80 deg C).The reaction proceeds regio- and stereospecifically.

Full text of DOI:10.1007/BF00479360

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