DIELS-ALDER REACTIONS OF 2-AZADIENES. DIASTEREOSELECTIVE SYNTHESES OF 2-AZABICYCLOOCTAN-2-ONES AND OF 2,3,4-SUBSTITUTED CYCLOHEXANONES

DOI: 10.1016/S0040-4039(00)80550-X

Source and publish data:

Tetrahedron Letters p. 4573 - 4576 (1988)

Update date:2022-09-26

Topics:

Authors:

Rivera, M.

Lamy-Schelkens, H.

Sainte, F.

Mbiya, K.

Ghosez, L.

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Article abstract of DOI:10.1016/S0040-4039(00)80550-X

Glutarimide is readily disilylated to yield the cyclic 2-azadiene 1 which reacts with open-chain dienophiles with surprisingly high exo-selectivity.The resulting 2-aza-bicyclo<2.2.2>octan-3-ones are stereoselectively transformed into substituted cyclohexa

Full text of DOI:10.1016/S0040-4039(00)80550-X

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