Tetrahedron Letters p. 4573 - 4576 (1988)
Update date:2022-09-26
Topics:
Rivera, M.
Lamy-Schelkens, H.
Sainte, F.
Mbiya, K.
Ghosez, L.
Glutarimide is readily disilylated to yield the cyclic 2-azadiene 1 which reacts with open-chain dienophiles with surprisingly high exo-selectivity.The resulting 2-aza-bicyclo<2.2.2>octan-3-ones are stereoselectively transformed into substituted cyclohexa
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