Towards stable di-carba analogues of guanofosfocins

DOI: 10.1016/j.tetlet.2011.02.102

Source and publish data:

Tetrahedron Letters p. 2940 - 2942 (2011)

Update date:2022-08-03

Topics:

Authors:

Duchek, Jan

Huang, Mu-Hua

Vasella, Andrea

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Article abstract of DOI:10.1016/j.tetlet.2011.02.102

Guanofosfocins are strong inhibitors of chitin synthases, but also very prone to hydrolytic cleavage. Two advanced intermediates 15 and 20 for the synthesis of stable di-carba-guanofosfocins were prepared via ester 11. Acylation of the allylic C-glycoside

Full text of DOI:10.1016/j.tetlet.2011.02.102

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