New Chirons from D-Glucose. Regio- and Diastereoselective C-C Bond Forming Reactions Exploiting Novel Aldotetrafuranose Acetates as Chiral Synthetic Equivalents of Tartaric Aldehydes

DOI: 10.1021/jo00278a022

Source and publish data:

Journal of Organic Chemistry p. 4100 - 4105 (1989)

Update date:2022-07-31

Topics:

Authors:

Dhavale, Dilip D.

Tagliavini, Emilio

Trombini, Claudio

Umani-Ronchi, Achille

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Article abstract of DOI:10.1021/jo00278a022

Two differentially protected tetrafuranose acetates 5 and 6 have been prepared from diacetone D-glucose in parallel short routes.They clearly act as chiral synthetic equivalents of D- and meso-tartaric aldehydes when exploited in Lewis acid promoted react

Full text of DOI:10.1021/jo00278a022

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