Stereochemistry of Thermal Ring Opening of Substituted 7-(Ethoxycarbo-nyl)bicyclooct-1(6)-enes and Related Substances.

DOI: 10.1021/jo00271a004

Source and publish data:

Journal of Organic Chemistry p. 2267 - 2268 (1989)

Update date:2022-07-30

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Authors:

Piers, Edward

Lu, Yee-Fung

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Article abstract of DOI:10.1021/jo00271a004

Thermally driven ring openings of the substituted 3-formylcyclobutenes 16 and 26 occur with exclusive inward rotation of the formyl group.Thermolysis of the ester 13 results in predominant formation of the ester diene 17 (outward rotation of CO2Et), while

Full text of DOI:10.1021/jo00271a004

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