Journal of the Chemical Society. Chemical communications p. 63 - 65 (1989)
Update date:2022-07-29
Topics:
Hamel, Pierre
Girard, Yves
Atkinson, Joseph G.
The rearrangement of indol-3-yl sulphides (1) indol-2-yl sulphides (4), catalysed by proton acids, unexpectedly proceeds by an intermolecular mechanism involving initial disproportionation to an indole-2,3-diyl bis-sulphide (2) and an indole (3), followed by a reaction between (2) and (3) to yield the rearranged product (4).
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