Tetrahedron Letters p. 6097 - 6100 (1988)
Update date:2022-08-02
Topics:
Collin, J.
Kagan, H. B.
Reaction of t-BuBr with SmCp2 and CO leads to the formation of different carbonylation products according to experimental conditions. tBu-CH(OH)-CH(OH)-tBu is obtained if the reaction is followed by hydrolysis. tBu-CO-CH(OH)-C6H13 is produced if the carbonylation of tBuBr is followed by addition of heptanal.The product tBu-CO-CO-CH(OH)-tBu which has incorporated three CO units, has also been isolated in a low yield.
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