STEREOCHEMICAL CONTROL IN THE SYNTHESIS OF TETRAHYDROFURANS BY CYCLISATION OF DIOLS WITH PHENYLTHIO MIGRATION

DOI: 10.1016/S0040-4039(00)80634-6

Source and publish data:

Tetrahedron Letters p. 4885 - 4888 (1988)

Update date:2022-08-02

Topics:

Authors:

Aggarwal, Varinder K.

Coldham, Iain

McIntyre, Sara

Sansbury, Francis H.

Villa, Maria-Jesus

Warren, Stuart

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Article abstract of DOI:10.1016/S0040-4039(00)80634-6

Cyclisation of diols with PhS migration leads to tetrahydrofurans by inversion at both the migration origin and terminus.Cyclisation to a secondary migration terminus is controlled by stereochemical factors.

Full text of DOI:10.1016/S0040-4039(00)80634-6

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