HYDROLYSIS OF ALLYLSILANES COORDINATED TO PLATINUM(II)

DOI: 10.1016/S0022-328X(00)98602-9

Source and publish data:

Journal of Organometallic Chemistry p. 201 - 208 (1983)

Update date:2022-08-04

Topics:

Authors:

Fitch, John W.

Brown, Michael

Hall, Nancy H.

Mebe, Paul P.

Owens, Kevin A.

Roesch, Michael R.

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Article abstract of DOI:10.1016/S0022-328X(00)98602-9

Allylsilane complexes of formula, K, <(acac)-PtCl(CH2=CHCH2SiMe3)> and trans- where py = a pyridine base, have been prepared, isolated and hydrolyzed.In the cases studied the major product of the hydrolysis is an allyl-platinum(II) complex rather than propene.Propene complexes can be formed, however, if the hydrolysis is conducted at sufficiently low pH.

Full text of DOI:10.1016/S0022-328X(00)98602-9

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