Tetrahedron p. 3851 - 3868 (1988)
Update date:2022-07-30
Topics: NMR spectroscopy Cyclization Stereoselective Chiral Catalyst Reaction Optimization allylsilanes Stannanes Stereocenter
Schinzer, Dieter
Allagiannis, Christos
Wichmann, Sabine
The syntheses and additions of allylsilanes, and -stannanes to enones and dienones forming spiro- and fused-bicyclic products are described.The stereoselectivity observed is dependent on the Lewis acid used.The tin terminator reverses the stereoselectivit
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