
Journal of the Chemical Society, Dalton Transactions p. 2221 - 2224 (1988)
Update date:2022-08-02
Topics:
Demarcq, Michel C.
The thermal redistribution of P4S10 with (RS)3PS (R=alkyl or aryl) generates metaphosphorotrithioic esters (RSPS2)2 and relatively smaller amounts of symmetrical <(RS)2P(S)>2S as 'middle' and 'end' species respectively.Reacting P4S10 with thiols affords similar mixtures.With dithiols HS(CH2)nSH (n=2 or 3), no 'middle' compound was obtained but only 'end' and 'ortho' derivatives, chiefly
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(1988)Doi:10.1039/b917660h
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