Catalytic enantioselective mannich-type reaction via a chiral silver enolate

DOI: 10.1021/ol403075u

Source and publish data:

Organic Letters p. 86 - 89 (2014)

Update date:2022-07-30

Topics:

Authors:

Yanagisawa, Akira

Lin, Yuqin

Miyake, Ryoji

Yoshida, Kazuhiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ol403075u

A catalytic asymmetric Mannich-type reaction of alkenyl trichloroacetates with aldimines was achieved using SEGPHOS·AgOTf as the chiral precatalyst and N,N-diisopropylethylamine as the base precatalyst in the presence of 2,2,2-trifluoroethanol. Optically

Full text of DOI:10.1021/ol403075u

Products guided by the article

Product name:(2S,1’S)-2-[(phenylamino)(4-(trifluoromethyl)phenyl)methyl]cyclohexanone

Cas No:1215119-74-6

R&D Labs maybe for 1215119-74-6

Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
VanderArk International Limited

Contact:86-10-82437576

Address:Qing He
A.M FOOD CHEMICAL CO., LIMITED

Contact:86-531-87100375

Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Shanghai Egoal Chemical Co.,Ltd

Contact:+86-21-50333091

Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai

Relevant to this article

Total synthesis of polyene natural product dihydroxerulin by mild organocatalyzed dehydrogenation of alcohols

Doi:10.1002/chem.201103325
(2012)
One-pot three-component synthesis of benzo[f]thiopyrano[3,4-b]quinolin- 11(8H)-one derivatives

Doi:10.1002/jhet.1727
(2014)
Cyclic tetrapeptides with-SS-bridging between amino acid side chains for potent histone deacetylases' inhibition

Doi:10.1007/s00726-013-1527-8
(2013)
[PdA (IPr*) (cinnamyl)Cl]: An efficient pre-catalyst for the preparation of tetra-ortho-substituted biaryls by Suzuki-Miyaura cross-coupling

Doi:10.1002/chem.201104009
(2012)
Solution-processable 1,3,5-tri(9-anthracene)-benzene cored propeller-shaped materials with high T_g for blue organic light-emitting diodes

Doi:10.1016/j.orgel.2011.06.025
(2011)
Synthesis of 4-thiazolidine derivatives of 6-nitroindazole: Pharmaceutical importance

Doi:10.4067/s0717-97072012000100018
(2012)

Article Doi