CYCLOPENTAANNULATION REACTIONS BETWEEN NITROCYCLOALKENES AND DIACETYL MORPHOLINO ENAMINE

DOI: 10.1016/S0040-4020(01)86222-0

Source and publish data:

Tetrahedron p. 6921 - 6928 (1988)

Update date:2022-09-26

Topics:

Authors:

Felluga, F.

Nardin, G.

Nitti, P.

Pitacco, G.

Valentin, E.

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Article abstract of DOI:10.1016/S0040-4020(01)86222-0

Hexahydro-pentalene and -indene nitroalcohols are obtained by reaction of 3-(4-morpholinyl)-3-buten-2-one with cyclic nitroolefins.With 1-nitro-cyclohexene a <4+2> heterocyclization intermediate is separated, while an unusual product of double addition is obtained from the hexahydro-pentalene derivative in aqueous acidic medium.

Full text of DOI:10.1016/S0040-4020(01)86222-0

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