peri-Diketones with the Ring System of Cyclo-octanaphthalene

DOI: 10.1039/P19890000215

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 215 - 220 (1989)

Update date:2022-07-31

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Authors:

Jackson, David A.

Lacy, Philip H.

Smith, Donald C. C.

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Article abstract of DOI:10.1039/P19890000215

peri-Diketones of naphthalene having an eight-membered ring are obtained by oxidative cleavage of cyclopentacenaphthylenes prepared from acenaphthylene-1,2-dione.Cyclo-octanaphthalenes with two peri β-keto ester ketone carbonyl groups exist as mono-enols.The parent 9,10-dihydrocyclo-octanaphthalene-7,11(8H)-dione is a stable though reactive diketone, reduced to a pinacol with exceptional ease and forming stable adducts with water or methanol.

Full text of DOI:10.1039/P19890000215

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