FORMATION OF COLEON A SKELETON FROM (-)-ABIETIC ACID

DOI: 10.1246/cl.1980.425

Source and publish data:

Chemistry Letters p. 425 - 428 (1980)

Update date:2022-08-03

Topics:

Authors:

Matsumoto, Takashi

Imai, Sachihiko

Ondo, Kenji

Takeyama, Nobuaki

Fukui, Kenji

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Article abstract of DOI:10.1246/cl.1980.425

By the treatment of Δ⁶-6-hydroxy-5βH-dehydroabietic acid (18-6)-lactone with potassium hydrogensulfate or conc. sulfuric acid, the B ring aromatization and the C1-C10 bond cleavage occurred to give 1,10-secoabietane derivatives possessing coleon A skeleton.

Full text of DOI:10.1246/cl.1980.425

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