Tetrahedron Letters p. 6593 - 6596 (1988)
Update date:2022-08-04
Topics:
Landen, Harald
Margraf, Birgit
Martin, Hans-Dieter
Cycloaddition reactions of diazoalkanes, with R = H and R' = H, alkyl, aryl or alkoxycarbonil, yield syn-adducts with dichlorocyclobutene.Diphenylnitrilimine, however, mainly undergoes anti-additions.Two phenomena not described as yet will be discussed for the interpretation: the influence of substituents in 3,4-position on the out-of-plane distortions of the olefinic hydrogen atoms and vicinal torsional interactions in model transition structures.
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Doi:10.1021/ol100446p
(2010)Doi:10.1021/ja100517v
(2010)Doi:10.1016/S0040-4020(01)89795-7
(1988)Doi:10.1007/s10593-009-0387-3
(2009)Doi:10.1016/j.jorganchem.2009.11.008
(2010)Doi:10.1107/S0108270109031175
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