Co-ordinatively Unsaturated Diphosphine Platinum(II) Alkyl Cations: A New Class of β-Agostic Complexes

DOI: 10.1039/c39880000926

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 926 - 928 (1988)

Update date:2022-09-26

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Authors:

Carr, Nicholas

Dunne, Barry J.

Orpen, A. Guy

Spencer, John L.

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Article abstract of DOI:10.1039/c39880000926

Treatment of tris(norbornene)platinum with diphosphines and subsequent protonation affords a series of cationic complexes (1+) (L2 = peralkyldiphosphine) in which the norbornyl ligand binds to platinum via ?-alkyl and β-C-H agostic interact

Full text of DOI:10.1039/c39880000926

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