BICYCLO NONANE APPROACH TO PINGUISANE TERPENOIDS.TOTAL SYNTHESIS OF (+/-) PINGUISONE

DOI: 10.1016/S0040-4020(01)86187-1

Source and publish data:

Tetrahedron p. 4837 - 4846 (1988)

Update date:2022-07-29

Topics:

Authors:

Gambacorta, A.

Botta, M.

Turchetta, S.

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Article abstract of DOI:10.1016/S0040-4020(01)86187-1

The total synthesis of (+/-) pinguisone 1, the sterically crowded unusual <5-6> fused-ring sesquiterpene, was accomplished by synthetic elaboration of the 3β,3aβ,7,7aβ-tetramethylbicyclo <4.3.0> non-6-en-1-one 2a prepared by acid catalyzed rearrangement o

Full text of DOI:10.1016/S0040-4020(01)86187-1

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