Carbohydrate Research p. 13 - 20 (1989)
Update date:2022-08-05
Topics:
Nifantev, Nikolay E.
Backinowsky, Leon V.
Kochetkov, Nikolay K.
Replacement of AcO-3 in methyl 2,3-di-O-acetyl-4-O-trityl-β-D-xylopyranoside with a benzyl group greatly increases the 1,2-trans-stereoselectivity of glycosylation with D-xylopyranose 1,2-O-(1-Cyanoethylidene) derivative.Anomerisation of methyl 2-O-benzyl-β-D-xylopyranoside derivatives occured under the action of triphenylmethylium perchlorate.
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