An in situ generated ruthenium catalyst for the Tishchenko reaction

DOI: 10.1002/adsc.200900701

Source and publish data:

Advanced Synthesis and Catalysis p. 305 - 308 (2010)

Update date:2022-08-05

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Authors:

Simon, Marc-Olivier

Darses, Sylvain

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Article abstract of DOI:10.1002/adsc.200900701

A simple and efficient catalytic system for the selective dimerization of aldehydes, the Tishchenko reaction, is described. High yields of symmetrical esters were generally achieved using an in situ generated ruthenium catalyst in association with the electron-rich and hindered cyclohexyl-(diphenyl)phosphane (CyPPh₂) ligand.

Full text of DOI:10.1002/adsc.200900701

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