Carbamoylmethyl radical cyclization: Formal synthesis of (-)-trachelanthamidine

DOI: 10.1248/cpb.40.2308

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2308 - 2312 (1992)

Update date:2022-09-26

Topics:

Authors:

Sato Sato

Tsujimoto

Matsubayashi

Ishibashi

Ikeda Ikeda

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Article abstract of DOI:10.1248/cpb.40.2308

Tributyltin hydride-mediated radical cyclization of the (2S)-N-(α-chloroacetyl)-2-ethenylpyrrolidines 13a, b and 15 and the bis(phenylthio)acetyl congener 14 derived from (S)-prolinol gave (1R,7aS)-hexahydro-1-methyl-3H-pyrrolizin-3-one (17) and its deriv

Full text of DOI:10.1248/cpb.40.2308

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