Synthesis of Optically Active Fjord-Region 11,12-Diol 13,14-Epoxides and the K-Region 9,10-Oxide of the Carcinogen Benzochrysene

DOI: 10.1021/jo00276a009

Source and publish data:

Journal of Organic Chemistry p. 3533 - 3544 (1989)

Update date:2022-08-05

Topics:

Authors:

Bushman, Daniel R.

Grossman, Scott J.

Jerina, Donald M.

Lehr, Roland E.

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Article abstract of DOI:10.1021/jo00276a009

Optically pure enantiomers of the diastereomeric pair of benzochrysene-11,12-diol 13,14-epoxides (Scheme VI) were synthesized from (11R,12R)- and (11S,12S)-dihydroxy-11,12-dihydrobenzochrysenes (16(R,R) and 16(S,S)).Two routes were employed to synth

Full text of DOI:10.1021/jo00276a009

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