Journal of Organic Chemistry p. 4165 - 4168 (1989)
Update date:2022-08-05
Topics:
Vogler, B.
Bayer, R.
Meller, M.
Kraus, W.
Schell, Fred M.
Cyclic enaminoes 1-7 were prepared and photolyzed.Compounds 1-4 reacted as expected to provide aza-De Mayo products 10 and 11, whereas 5 provided enaminone 12 in a novel photo-aza-Claisen rearrangement.Compounds 6 and 7 gave photo-aza-Claisen products 13 and 16, respectively, along with aza-De Mayo product 15 and 2 + 2 cycloaddition product 17, respectively.
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(2012)