EFFICIENT SYNTHESIS OF NATURAL ENANTIOMER OF SPOROGEN-AO 1 (13-DESOXYPHOMENONE), A SPOROGENIC SESQUITERPENE FROM ASPERGILLUS ORYZAE

DOI: 10.1016/S0040-4020(01)86136-6

Source and publish data:

Tetrahedron p. 4339 - 4350 (1988)

Update date:2022-08-03

Topics: Enantiomer Efficient Synthesis Experimental terms Sesquiterpene

Authors:

Kitahara, Takeshi

Kurata, Hitoshi

Mori, Kenji

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Article abstract of DOI:10.1016/S0040-4020(01)86136-6

An efficient total synthesis of (+)-sporogen-AO 1 (13-desoxyphomenone) 1 was achieved in 20 steps from ethyl (1R,2S)-5,5-ethylenedioxy-2-hydroxycyclohexanecarboxylate 3 in 8.3percent overall yield.The optically active 3 with 98.4percent e.e. was easily ob

Full text of DOI:10.1016/S0040-4020(01)86136-6

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