
Tetrahedron Letters p. 6947 - 6948 (1988)
Update date:2022-08-03
Topics:
Moriya, Tsukasa
Handa, Yuichi
Inanaga, Junji
Yamaguchi, Masaru
Ferrulactone I, a 11-membered macrolide insect pheromone, was synthesized straightforwardly from geraniol with the efficient use of two SmI2-promoted reactions in the key steps; intramolecular Reformatsky reaction and a novel regioselective reduction of allylic benzoate.
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