Chemistry of Heterocyclic Compounds p. 854 - 858 (1991)
Update date:2022-07-31
Topics:
Mayants, A. G.
Klimenko, V. S.
Erina, V. V.
Pyreseva, K. G.
Gordeichuk, S. S.
et al.
1(2)-Methyl-5-aminotetrazoles and 2-(β-cyanoethyl)-5-aminotetrazole are nitrated by tetranitromethane in the presence of bases with the formation of salts of the corresponding 5-nitroaminotetrazole derivatives.In contrast to this, decyanoethylation takes place in nitration of 1-(β-cyanoethyl)-5-aminotetrazole by tetranitromethane with the formation of 5-nitroaminotetrazole salt.The structure of the 2-methyl-5-nitroaminotetrazole salts (using the 2-methyl-5-nitroaminotetrazole potassium salt) was confirmed by x-ray structural analysis.
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