Synthesis and Reactions of N-Alkyl-O-diphenylphosphinylhydroxylamines and N-Alkyl-N-diphenylphosphinylhydroxylamines

Article abstract of DOI:10.1055/s-1988-27749

Reaction of a series of primary amines with bis(diphenylphosphinyl)peroxide conveniently leads to N-alkyl-O-diphenylphosphinylhydroxylamines.These compounds rearrange on heating to the thermodynamically more stable N-phosphinylated derivatives, the N-alkyl-N-diphenylphosphinylhydroxylamines (N-alkyldiphenylphosphinohydroxamic acids).