Syntheses of (+/-)-Alchorneine nad (+/-)-Isoalchorneine

DOI: 10.1021/jo00280a009

Source and publish data:

Journal of Organic Chemistry p. 4494 - 4496 (1989)

Update date:2022-09-26

Topics:

Authors:

Buechi, George

Rodriguez, Abimael D.

Yakushijin, Kenichi

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Article abstract of DOI:10.1021/jo00280a009

The two title alkaloids have been prepared from cyanamide in four and three synthetic operations, respectively, using palladium-assisted cyclizations in the critical steps.The α-effect causes the hydroxylamino nitrogen atom in methoxyguanidine to be the m

Full text of DOI:10.1021/jo00280a009

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