ALDOL REACTIONS OF METHYLKETONES USING CHIRAL BORON REAGENTS: A REVERSAL IN ALDEHYDE ENANTIOFACE SELECTIVITY

DOI: 10.1016/S0040-4039(00)95300-0

Source and publish data:

Tetrahedron Letters p. 997 - 1000 (1989)

Update date:2022-08-03

Topics:

Authors:

Paterson, Ian

Goodman, Jonathan M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95300-0

The enantioselectivity of aldol additions of methylketones to aldehydes using(-)-(Ipc)2BOTf, (-)-1, and Prⁱ2NEt is generally lower(53-78percent ee) than that for the corresponding ethylketone reaction and occurs with the opposite sense of aldeh

Full text of DOI:10.1016/S0040-4039(00)95300-0

Products guided by the article

Product name:4-Penten-1-one, 3-hydroxy-4-methyl-1-phenyl-, (R)-

Cas No:123072-88-8

R&D Labs maybe for 123072-88-8

KAIYUAN CHEMICAL COMPANY LIMITED.

website:http://www.kaiyuanchem.com

Contact:+86-22-59891255/66/77

Address:B-2205, Kuangshi International Building, Yingbin Road, XiangLuo Bay Business District, Binhai New area, Tianjin, China.
Xinjiang Fufeng Biotechnologies Co., Ltd.

Contact:+86-539-7287111

Address:GANQUANPU INDUSTRIAL PARK, ECONOMIC AND TECHNOLOGICAL DEVELOPMENT AREA (TOUTUNHE DISTRICT) OF URUMQI
SPRING CHEMICAL INDUSTRY CO.,LTD

Contact:86-187-66672125

Address:linchi industry park.zouping
KA-SHING Business Trade Macau Co., Ltd.

Contact:00853-28430045

Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao
Clearsynth Labs Limited

Contact:+91 - 22 - 26355700

Address:17, Lotus Business Park, Andheri West

Relevant to this article

Synthesis and fluorescence and electrochemical properties of D-π-A structural isomers of benzofuro[2,3-c]oxazolo[4,5-a]carbazole-type and benzofuro[2,3-c]oxazolo[5,4-a]carbazole-type fluorescent dyes

Doi:10.1039/c003526b
(2010)
Gold(I)-Catalysed Hydroarylation of Lactam-Derived Enynes as an Entry to Tetrahydrobenzo[g]quinolines

Doi:10.1002/ejoc.201901599
(2020)
Phosphinosulphoxide rhodium complexes. Synthesis, crystal structure, and catalytic chemistry of <(2,3,5,6-η)-bicyclo<2.2.1>-hepta-2,5-diene>rhodium(I)trifluoromethanesulphonate and asymmetric analogues

Doi:10.1016/0022-328X(88)83094-8
(1988)
Carbon-fluorine bond activation in thermolysis reactions of the osmium(IV) perfluorothiolate compounds [Os(SC₆F₅) ₄(P(C₆H₄X-4)₃)] (X = CF₃, Cl, F, H, CH₃, and OCH₃)

Doi:10.1021/om901065g
(2010)
Discovery of a novel HDAC3 selective inhibitor and its evaluation in lymphoma model

Doi:10.1002/bkcs.10619
(2016)
Synthesis and structure of diamine bis(phenolate) complexes containing the Ti(OEt)-O-Ti(OEt) function

Doi:10.1016/j.poly.2010.02.006
(2010)

Article Doi