Phosphinosulphoxide rhodium complexes. Synthesis, crystal structure, and catalytic chemistry of -hepta-2,5-diene>rhodium(I)trifluoromethanesulphonate and asymmetric analogues

DOI: 10.1016/0022-328X(88)83094-8

Source and publish data:

Journal of Organometallic Chemistry p. 233 - 248 (1988)

Update date:2022-08-03

Topics:

Authors:

Alcock, Nathaniel W.

Brown, John M.

Evans, Phillip L.

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Article abstract of DOI:10.1016/0022-328X(88)83094-8

α-Phosphinosulphoxides are readly accessible by the reaction of α-lithioalkylsulphoxides with Ph2PCl, and are stable towards internal oxygen transfer when pure.The compound Ph2PCH2S(O)Ph thus prepared was shown to form a cationic rhodium bicyclo<2,2,1>hep

Full text of DOI:10.1016/0022-328X(88)83094-8

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Product name:{(2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}{P,O-diphenyl(phenylsulphinylmethyl)phosphine}rhodium(I) tetrafluorobotate

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