A Novel Generation and Behavior of Alkylfluorocarbenoids from α,α-Chlorofluoroalkyl Sulfoxides

DOI: 10.1246/cl.1989.309

Source and publish data:

Chemistry Letters p. 309 - 312 (1989)

Update date:2022-08-04

Topics:

Authors:

Uno, Hidemitsu

Semba, Fumihiko

Tasaka, Tadataka

Suzuki, Hitomi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1989.309

α,α-Chlorofluoroalkyl sulfoxides undergo nucleophilic desulfinylation with a Grignard reagent to give alkylfluorocarbenoids which collapse into cis-fluoroalkenes in the presence of copper(I) iodide.

Full text of DOI:10.1246/cl.1989.309

Products guided by the article

Product name:1-chloro-1-fluoro-4-phenylbutyl phenyl sulfoxide

Cas No:123133-12-0

R&D Labs maybe for 123133-12-0

Hangzhou Haiqiang Chemical Co.,Ltd.

Contact:+86-571-86960370

Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

website:http://www.bjgreenchem.com/

Contact:+86-427-6515887

Address:301,302, 3rd Floor, Building C-7, Dongsheng Science Park, Northern Territory, Zhongguancun, No. 66, Xixiaokou Road, Haidian District, Beijing
Shaanxi King Stone Enterprise Company Limited

Contact:86-29-88353805,13609285751

Address:.209 Keji Road Hi-Tech industrial Develpment Zone .Xian China
Tianjin Pharmacn Medical Technology Co.,Ltd.

Contact:86-22-60122566ext.866(English),23359620

Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
Wuxi Innopal International Trade CO.,LTD

Contact:+86-510-80711901-8003

Address:Room 402,Building 5,Longze Garden,No.17,South huanjiu Road,Yixing City, Jiangsu,China

Relevant to this article

Design, synthesis, crystal structures, and antimicrobial activity of sulfonamide boronic acids as β-lactamase inhibitors

Doi:10.1021/jm101015z
(2010)
A General Protocol for the Polycondensation of Thienyl N-Methyliminodiacetic Acid Boronate Esters to Form High Molecular Weight Copolymers

Doi:10.1021/jacs.6b07666
(2016)
Ruthenium(II) 2,2′-bipyridine complexes incorporating substituted phenylazo-(2-(phenylthio))phenylmethine ancillary ligands. Synthesis, crystal structure, spectroscopic and redox properties

Doi:10.1007/s11243-010-9407-5
(2010)
Ruthenium carbene mediated [2+2+2] cyclotrimerizations

Doi:10.1055/s-0030-1258521
(2010)
Synthesis, Characterization and Catalytic Application of MCM 41 Supported Phenanthrolinium Dibromide Catalyst for Aza-Michael Addition Reaction in Aqueous Medium

Doi:10.1007/s10562-016-1743-4
(2016)
Alteration of cross-linking selectivity with the 2′-OMe analogue of 2-amino-6-vinylpurine and evaluation of antisense effects

Doi:10.1016/j.bmcl.2010.08.027
(2010)

Article Doi