A Novel Generation and Behavior of Alkylfluorocarbenoids from α,α-Chlorofluoroalkyl Sulfoxides

DOI: 10.1246/cl.1989.309

Source and publish data:

Chemistry Letters p. 309 - 312 (1989)

Update date:2022-08-04

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Authors:

Uno, Hidemitsu

Semba, Fumihiko

Tasaka, Tadataka

Suzuki, Hitomi

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Article abstract of DOI:10.1246/cl.1989.309

α,α-Chlorofluoroalkyl sulfoxides undergo nucleophilic desulfinylation with a Grignard reagent to give alkylfluorocarbenoids which collapse into cis-fluoroalkenes in the presence of copper(I) iodide.

Full text of DOI:10.1246/cl.1989.309

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