Costruction of Fused-Ring Skeletons Based on Photochemical Rearrangements of Bicyclooct-6-en-2-ones and Application to a Total Synthesis of (+/-)-Δ9(12)-Capnellene

DOI: 10.1021/jo00284a003

Source and publish data:

Journal of Organic Chemistry p. 5411 - 5413 (1989)

Update date:2022-08-04

Topics:

Authors:

Uyehara, Tadao

Furuta, Toshiaki

Akamatsu, Minoru

Kato, Tadahiro

Yamamoto, Yoshinori

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00284a003

A method for preparation of bicyclo<3.3.0>oct-7-en-2-ones has been developed on the basis of the photochemical <1,3>-acyl migration of 8,8-disubstituted bicyclo<3.2.1>oct-6-en-2-ones and applied to a total synthesis of (+/-)-Δ⁹⁽¹²⁾-capnellene, a linear triquinane.

Full text of DOI:10.1021/jo00284a003

Products guided by the article

Product name:(1S,6S)-8-Benzyl-6-methyl-tricyclo[4.2.0.0^2,8]octan-3-one

Cas No:123185-59-1

R&D Labs maybe for 123185-59-1

Heliosense Biotechnologies, Inc.

Contact:+86-592-5667290

Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
ClickChem Technology Co., Limited

Contact:+86-0310-6519966/0531-52893837

Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
Shanghai PuYi Chem-Tech Co.,Ltd.

Contact:+86-21-57687505-227

Address:3 Floor, Building 11, No 201 MinYi Road, Songjiang District, Shanghai 201612, China
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
Wuhan Hanye Chemical New Material Co.,Ltd

Contact:+86-27-85308141

Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China

Relevant to this article

Synthesis of quinazolines from N -(2-Nitrophenylsulfonyl)iminodiacetate and α-(2-Nitrophenylsulfonyl)amino ketones via 2 H -indazole 1-oxides

Doi:10.1021/jo100784z
(2010)
Progesterone-adenine hybrids as bivalent inhibitors of P-glycoprotein- mediated multidrug efflux: Design, synthesis, characterization and biological evaluation

Doi:10.1016/j.steroids.2012.07.010
(2012)
Highly diastereo- and enantioselective michael additions of 3-substituted oxindoles to maleimides catalyzed by chiral bifunctional thiourea-tertiary amine

Doi:10.1021/ol100822k
(2010)
A comprehensive study of substituent effects on poly(dibenzofulvene)s

Doi:10.1039/C6NJ02861F
(2017)
Enantioselective Michael addition of ketones to maleimides catalyzed by bifunctional monosulfonyl DPEN salt

Doi:10.1039/c0cc00774a
(2010)
Gold-Catalyzed Tandem 1,3-Migration/Double Cyclopropanation of 1-Ene-4,n-diyne Esters to Tetracyclodecene and Tetracycloundecene Derivatives

Doi:10.1021/acs.orglett.6b02404
(2016)

Article Doi