Conversion of Amides to S-Alkyl and S-Aryl Thioesters via Nitrosoamides and Nitroamides

DOI: 10.1055/s-1989-27234

Source and publish data:

Synthesis p. 305 - 306 (1989)

Update date:2022-09-26

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Authors:

Berenguer, Ramon

Garcia, Jordi

Vilarrasa, Jaume

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Article abstract of DOI:10.1055/s-1989-27234

Thiolates react at room temperature with nitrosoamides and, even more rapidly, with nitroamides to afford good yields of S-alkyl and S-aryl thioesters; by-products arising from N-to-S transnitrosations and transnitrations are practically not observed.

Full text of DOI:10.1055/s-1989-27234

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