DIASTEREOSELECTIVE SYNTHESIS OF BICYCLOOCTANES BY DOUBLE MICHAEL ADDITION

DOI: 10.1016/S0040-4039(00)95249-3

Source and publish data:

Tetrahedron Letters p. 547 - 550 (1989)

Update date:2022-09-26

Topics:

Authors:

Spitzner, Dietrich

Wagner, Peter

Simon, Arndt

Peters, Karl

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Article abstract of DOI:10.1016/S0040-4039(00)95249-3

Several chiral acrylates (7b-f) react with kinetically controlled generated lithium dienolate 6a to form chiral bicyclo<2.2.2>octanes 4 with modest d.e..It was found, that the diastereoselection is improved, when the corresponding trimethylsilyl ether 6b

Full text of DOI:10.1016/S0040-4039(00)95249-3

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