Tetrahedron Letters p. 547 - 550 (1989)
Update date:2022-09-26
Topics:
Spitzner, Dietrich
Wagner, Peter
Simon, Arndt
Peters, Karl
Several chiral acrylates (7b-f) react with kinetically controlled generated lithium dienolate 6a to form chiral bicyclo<2.2.2>octanes 4 with modest d.e..It was found, that the diastereoselection is improved, when the corresponding trimethylsilyl ether 6b
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