Palladium-Catalyzed Polyene Cyclizations of Trienyl Triflates

DOI: 10.1021/jo00286a009

Source and publish data:

Journal of Organic Chemistry p. 5846 - 5848 (1989)

Update date:2022-07-30

Topics:

Authors:

Carpenter, Nancy E.

Kucera, David J.

Overman, Larry E.

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Article abstract of DOI:10.1021/jo00286a009

Spirotricyclic dienones are conveniently prepared by palladium-catalyzed cyclizations of enol triflate derivatives of 2-dienyl-1,3-cyclohexanediones.The use of chiral (nonracemic) ligands allows assembly of these products with moderate enantioselectivity,

Full text of DOI:10.1021/jo00286a009

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