
Tetrahedron p. 2223 - 2236 (1989)
Update date:2022-08-04
Topics: Structural Confirmation
Groszek, Grazyna
Kurek-Tyrlik, Alicja
Wicha, Jerzy
A representative cardenolide 1 was synthesized starting from 17-oxo-14α-H androstane derivative 2, with the introduction of the hydroxy group into the position 14 prior to construction of the butenolide ring.Key steps of the synthesis involve: (1) hydroxy
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