Stereoselective Synthesis of (+/-)-Trichodiene

DOI: 10.1021/jo00182a038

Source and publish data:

Journal of Organic Chemistry p. 1464 - 1465 (1984)

Update date:2022-08-05

Topics:

Authors:

Snowden, Roger L.

Sonnay, Philippe

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Article abstract of DOI:10.1021/jo00182a038

A stereoselective synthesis of (+/-)-trichodiene (1) is described whose key step is the conversion of the tricyclic, homoallylic alcohol 3, via β-fragmentation of its potassium alkoxide 3a, to cyclopentanone 2.

Full text of DOI:10.1021/jo00182a038

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