?-Bonding to tetravalent main-group IV elements; an experimental effort

DOI: 10.1016/0022-328X(89)87164-5

Source and publish data:

Journal of Organometallic Chemistry p. 37 - 46 (1989)

Update date:2022-08-04

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Authors:

Janiak, Christoph

Schwichtenberg, Michael

Hahn, F. Ekkehardt

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Article abstract of DOI:10.1016/0022-328X(89)87164-5

Ph5C5GeCl3 (1) and Ph5C5SnCl3 (2) have been synthesized by oxidative addition of Ph5C5Cl to GeCl2 or SnCl2, respectively, and were characterized by 13C NMR and mass spectroscopy.Both compounds are fluxional in solution.The crystal structure of 1*0.5Et2O h

Full text of DOI:10.1016/0022-328X(89)87164-5

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