Tetrahedron p. 1105 - 1118 (1989)
Update date:2022-08-05
Topics:
Wang, Kung K.
Chu, Kai-Hsuan
Lin, Yuan
Chen, Jyun-Hung
Di- and trisubstituted alkenylstannanes were synthesized by selective conversion of the dialkylboryl moiety of 3 to the alkenylcopper followed by treatment with methanol or alkyl halides.By starting from conjugated terminal enynes to produce 3, 2-(trimethylstannyl)-1,3-butadienes were similarly synthesized.The readily available trisubstituted alkenylstannanes are useful precursors for the synthesis of stereochemically defined tetrasubstituted alkenes.
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