Tetrahedron Letters p. 2553 - 2554 (1989)
Update date:2022-07-29
Topics:
Saimoto, Hiroyuki
Kotani, Kazuya
Shigemasa, Yoshihiro
Suzuki, Makoto
Harada, Ken-ichi
2-<1,2-Dihydroxy-1-(hydroxymethyl)ethyl>-5-(2-hydroxyethyl)-4-methylthiazole (5) was isolated in the formose reaction catalyzed by thiamin*HCl, giving an insight into the reaction mechanism of benzoin type HCHO condensation to form dihydroxyacetone.
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Doi:10.1002/chem.200903521
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