ISOLATION OF AN INTERMEDIATE OF FORMOSE REACTION CATALYZED BY THIAMIN-HCl

DOI: 10.1016/S0040-4039(01)80448-2

Source and publish data:

Tetrahedron Letters p. 2553 - 2554 (1989)

Update date:2022-07-29

Topics:

Authors:

Saimoto, Hiroyuki

Kotani, Kazuya

Shigemasa, Yoshihiro

Suzuki, Makoto

Harada, Ken-ichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)80448-2

2-<1,2-Dihydroxy-1-(hydroxymethyl)ethyl>-5-(2-hydroxyethyl)-4-methylthiazole (5) was isolated in the formose reaction catalyzed by thiamin*HCl, giving an insight into the reaction mechanism of benzoin type HCHO condensation to form dihydroxyacetone.

Full text of DOI:10.1016/S0040-4039(01)80448-2

Products guided by the article

Product name:2-<1,2-dihydroxy-1-(hydroxymethyl)ethyl>-5-(2-hydroxyethyl)-4-methylthiazole

Cas No:124488-57-9

R&D Labs maybe for 124488-57-9

Ningbo Huajia Chemicals

Contact:+86-574-87065746

Address:10th Floor, No.787 Baizhang East Road,
Wuhan Shangrisyn chemicals Technology Co.,Ltd(expird)

Contact:+86-027-84466317 __ +86-15387123698

Address:wuhan - china
ChangZhou Mascotchem. Co.,Ltd.

website:http://www.mascotchem.com

Contact:86-519-85010339

Address:B-802,XingBei Building,391#,Tongjiang Middle Road New District,Changzhou,JS,China
Huangshan Honghui Pharm Technology Co., Ltd.(expird)

website:http://www.honghuichem.com

Contact:18855958372

Address:Qingshan Wan No.1,Nanyuan Kou,SheXian Huangshan City,Anhui Province
Longhui qunfeng Chemical Co., Ltd

Contact:86-731-82173407

Address:South-east Industrial Park, Longhui County, Hunan Province, China

Relevant to this article

Stereodivergent quaternization of 2-alkyl-2-p-tolylsulfinylacetonitriles: NMR spectroscopic evidence of planar and pyramidal benzylic carbanions

Doi:10.1002/chem.200903521
(2010)
Pheromone synthesis. Part 244: Synthesis of the racemate and enantiomers of (11Z,19Z)-CH503 (3-acetoxy-11,19-octacosadien-1-ol), a new sex pheromone of male Drosophila melanogaster to show its (S)-isomer and racemate as bioactive

Doi:10.1016/j.tet.2010.06.080
(2010)
Stereoisomeric 2-butylphenylsulfoxides and their binding modes in the adduct formation with an enantiopure dirhodium tetracarboxylate complex

Doi:10.1016/j.molstruc.2010.01.060
(2010)
Palladium-diphosphine complexes as catalysts for allylations with allyl alcohol

Doi:10.1016/j.molcata.2010.06.023
(2010)
The synthesis of, and characterization of the dynamic processes occurring in Pd(ii) chelate complexes of 2-pyridyldiphenylphosphine

Doi:10.1039/b918162h
(2010)
Isoxazole analogs of curcuminoids with highly potent multidrug-resistant antimycobacterial activity

Doi:10.1016/j.ejmech.2010.07.003
(2010)

Article Doi