FUNCTIONALIZED CHLOROENAMINES IN AMINOCYCLOPROPANE SYNTHESIS I. - BICYCLIC AND PENTACYCLIC LACTAMS FROM CARBAMOYLATED CHLOROENAMINES

DOI: 10.1016/S0040-4020(01)80145-9

Source and publish data:

Tetrahedron p. 3189 - 3202 (1989)

Update date:2022-08-05

Topics: Bicyclic Lactams Functionalized chloroenamines Aminocyclopropane synthesis

Authors:

Altmeier, Peter

Vilsmaier, Elmar

Wolmershaeuser, Gotthelf

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Article abstract of DOI:10.1016/S0040-4020(01)80145-9

Carbamoylated chloroenamines 15 were synthesized by acylation of cyclic enamines 11 with an arylisocyanate and subsequent chlorination using NCS.In the case of the seven membered enamine 11c a bicyclic β-lactam 16c was isolated as primary product, which r

Full text of DOI:10.1016/S0040-4020(01)80145-9

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