CHIRAL RECOGNITION IN THE REACTION OF THE ENOLATE DERIVED FROM 5-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph> WITH CIS- AND TRANS-2,3-EPOXYBUTANE: THE STEREOSELECTIVE SYNTHESIS OF CIS AND TRANS-βγ-DISUBSTITUTED-γ-LACTONES

DOI: 10.1016/S0040-4039(00)95262-6

Source and publish data:

Tetrahedron Letters p. 587 - 590 (1989)

Update date:2022-08-04

Topics: Stereoselective synthesis Chiral recognition Enolate

Authors:

Davies, Stephen G.

Middlemiss, David

Naylor, Alan

Wills, Martin

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Article abstract of DOI:10.1016/S0040-4039(00)95262-6

The reaction between the enolate derived from <(η⁵-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph> and cis- and trans-2,3-epoxybutane proceeds with a high degree of chiral recognition between the reagents (10:1) to give products which may be converted to β,γ-dimethyl-γ-lactones possessing trans- or cis- stereochemistry.

Full text of DOI:10.1016/S0040-4039(00)95262-6

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