CHIRAL RECOGNITION IN THE REACTION OF THE ENOLATE DERIVED FROM 5-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph> WITH CIS- AND TRANS-2,3-EPOXYBUTANE: THE STEREOSELECTIVE SYNTHESIS OF CIS AND TRANS-βγ-DISUBSTITUTED-γ-LACTONES

DOI: 10.1016/S0040-4039(00)95262-6

Source and publish data:

Tetrahedron Letters p. 587 - 590 (1989)

Update date:2022-08-04

Topics: Stereoselective synthesis Chiral recognition Enolate

Authors:

Davies, Stephen G.

Middlemiss, David

Naylor, Alan

Wills, Martin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95262-6

The reaction between the enolate derived from <(η⁵-C5H5)Fe(CO)(PPh3)COCH2OCH2Ph> and cis- and trans-2,3-epoxybutane proceeds with a high degree of chiral recognition between the reagents (10:1) to give products which may be converted to β,γ-dimethyl-γ-lactones possessing trans- or cis- stereochemistry.

Full text of DOI:10.1016/S0040-4039(00)95262-6

Products guided by the article

Product name:2-oxotetrahydrofuran-3-carboxylic acid benzyl ester

Cas No:124730-67-2

R&D Labs maybe for 124730-67-2

Shenyang Xinyihan Chemical Technology Co., Ltd.

Contact:+86-18525026267

Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
Anhui Eapearl Chemical Co., Ltd.

Contact:86-562-5858458

Address:358 South Huaihe Road
Shanghai HengXun Pharmaceutical Tech. Co., Ltd.

Contact:86-86-52730756

Address:Room 603, No. 240, Tianmuzhong Road, Zhabei, Shanghai, China
Shouguang Nuomeng Chemical Co., Ltd.

Contact:+86-536-5119508/18363669993

Address:Hou Zhen Industrial Park, Shouguang, Shandong, China
Lianyungang Ningkang Chemical Co., Ltd

Contact:.+86-518-88588008

Address:http://www.chemnk.com

Relevant to this article

Studies towards the synthesis of the fluorescent bases of phenylalanine transfer ribonucleic acids: Synthesis of 7-(2-hydroxy-3-methylbutyl)wye, a model for the minor base isolated from rat liver

Doi:10.1248/cpb.37.1221
(1989)
The specific character of the reaction of derivatives of 2-thioxo-2,3-dihydropyrimidin-4(1H)-one with iodomethane and alkyl chloromethyl sulfides

Doi:10.1007/s10593-010-0492-3
(2010)
Solid-state and solution-phase conformations of pseudoproline-containing dipeptides

Doi:10.1071/CH09151
(2009)
A facile synthesis of novel unsymmetrical N-(4-oxo-2-phenyl-3(4H)- quinazolinoyl)-N-(aryl)acetamidines

Doi:10.1016/j.cclet.2010.04.009
(2010)
Efficient Synthesis and Biological Activity of Novel Indole Derivatives as VEGFR-2 Tyrosine Kinase Inhibitors

Doi:10.1134/S1070363217120465
(2017)
A new odorless procedure for the synthesis of 2'-deoxy-6-thioguanosine and its incorporation into oligodeoxynucleotides

Doi:10.1080/15257770903155576
(2009)

Article Doi