Formation of 2-Imino-1,3-oxathioles and 2(3H)-Oxazolethione by the Rhodium(II) Acetate-Catalyzed Reaction of α-Diazocarbonyl Compounds with Isothiocyanates

DOI: 10.1246/bcsj.65.3088

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3088 - 3093 (1992)

Update date:2022-07-30

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Authors:

Ibata, Toshikazu

Nakano, Hirofumi

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Article abstract of DOI:10.1246/bcsj.65.3088

The rhodium(II) acetate-catalyzed reaction of various α-diazocarbonyl compounds with alkyl, phenyl, and benzoyl isothiocyanates gave 2-imino-1,3-oxathioles in good yields. 2(3H)-Oxazolethione was obtained as a byproduct only in the reaction of diazodimedo

Full text of DOI:10.1246/bcsj.65.3088

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