TRIETHYLBORANE-INDUCED STEREOSELECTIVE RADICAL ADDITION OF PERFLUOROALKYL IODIDES TO ACETYLENES

DOI: 10.1016/S0040-4039(00)99190-1

Source and publish data:

Tetrahedron Letters p. 3159 - 3162 (1989)

Update date:2022-08-05

Topics:

Authors:

Takeyama, Yoshihiro

Ichinose, Yoshifumi

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/S0040-4039(00)99190-1

Treatment of terminal or internal acetylenes bearing a variety of substituents with perfluoroalkyl iodides in the presence of a catalytic amount of triethylborane provides the corresponding perfluoroalkenes in good to excellent yields.The addition of perf

Full text of DOI:10.1016/S0040-4039(00)99190-1

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