TRIETHYLBORANE-INDUCED RADICAL ADDITION OF ALKYL IODIDES TO ACETYLENES

DOI: 10.1016/S0040-4039(00)99189-5

Source and publish data:

Tetrahedron Letters p. 3155 - 3158 (1989)

Update date:2022-09-26

Topics: Yield NMR spectroscopy Reaction Conditions Reaction Mechanism Radical Addition Acetylenes Alkyl iodides Triethylborane

Authors:

Ichinose, Yoshifumi

Matsunaga, Shin-ichiro

Fugami,Keigo

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/S0040-4039(00)99189-5

Treatment of terminal acetylenes (R¹C<*>CH) with secondary or tertiary alkyl iodides (R²I) in the presence of triethylborane provides the corresponding alkenyl iodides (R¹C(I)=CHR²) in good yields.

Full text of DOI:10.1016/S0040-4039(00)99189-5

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