A DIELS-ALDER APPROACH TO FUNCTIONALISED CIS-HYDROISOQUINOLINES

DOI: 10.1016/S0040-4039(01)80718-8

Source and publish data:

Tetrahedron Letters p. 4309 - 4312 (1989)

Update date:2022-08-05

Topics: Regioselectivity Lewis acid Column chromatography Yield NMR spectroscopy Catalyst Synthetic route HPLC (high-performance liquid chromatography) Diels-Alder Reaction Stereoselectivity Cycloaddition Tautomerization Dienophile Diene Functionalised Heterocycle Electron-withdrawing group Electron-donating group Retro-Diels-Alder

Authors:

Imbroisi, Dennis de Oliveira

Simpkins, Nigel S.

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Article abstract of DOI:10.1016/S0040-4039(01)80718-8

A new substituted 5,6-dihydro-2(1H)-pyridinone participates in highly efficient Diels-Alder reactions to give functionalised cis-hydroisoquinolines suitable for natural product synthesis.

Full text of DOI:10.1016/S0040-4039(01)80718-8

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Product name:Dimethyl 1,2,5,6-Tetrahydro-2-oxo-4-phenylpyridine-1,3-dicarboxylate

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