Journal of Chemical Physics p. 953 - 959 (1980)
Update date:2022-08-04
Topics: Relaxation
Courtieu, J.
Jullien, J.
Lai, Nguyen Thoi
Guillois, A.
Gonord, P.
et al.
A perdeuterated nematic liquid crystal N-(p-ethoxybenzylidene)-p-n-butylaniline (EBBA-d23, 98percent deuterium) was synthesized to study relaxation of small molecules dissolved in anisotropic solvents.Proton spin-lattice relaxation in the coupled A2 spin system of methylene chloride (CH2Cl2) was studied using both perhydro and perdeutero EBBA as the solvent.The relaxation was modeled as intramolecular dipole-dipole interactions plus other mechanisms that were treated collectively as fluctuating external random magnetic fields.Comparison of relaxation in EBBA and EBBA-d23 allowed the first experimental measurement of the correlation coefficient between external random fields at the two protons due to dipolar interactions of the methylene protons with the protons or deuterons of the solvent (78percent correlated).The selective nuclear Overhauser effect was also studied.
View MoreChangzhou Anyi Biochem Co., Ltd.(expird)
Contact:+86-519-88836158
Address:no,51 caoda
Xinchang Jiu Xin Pharmaceutical Co., Ltd
website:http://www.jiuxinpharm.com
Contact:86 137 5756 8585
Address:Poyang industry Park
website:http://www.maisonchem.com.cn
Contact:0086-311-83833777
Address:Leitou industrial district, xinji, shijiazhuang city, hebei province,
Contact:0572-2722882
Address:1201,F3,xinghuibandao,
Contact:
Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Doi:10.1002/chem.201501271
(2015)Doi:10.1002/chem.201001748
(2010)Doi:10.1002/ardp.201000016
(2010)Doi:10.1039/c4ra14379e
(2015)Doi:10.1002/ejoc.201000861
(2010)Doi:10.1246/cl.1988.1755
(1988)